東京工業大学大学院理工学研究科化学専攻
後藤研究室


Recent Publications

Original Papers and Reviews

2017

  1. "Modeling of the Bioactivation of an Organic Nitrate by a Thiol to Form a Thionitrate Intermediate", T. Sano, K. Shimada, Y. Aoki, T. Kawashima, S. Sase, and K. Goto, Molecules, 22, 19 (2017) .
  2. "The Concept of Preorganization", K. Goto, In Comprehensive Supramolecular Chemistry II, J. L. Atwood (ed.) vol 1, pp61-71 (2017).
  3. "Photochemically-Generated Thiyl Free Radicals Observed by X-ray Absorption Spectroscopy", E. Sneeden, M. Hackett, J. Cotelesage, R. Prince, M. Barney, K. Goto, E. Block, I. Pickering, and G. George, J. Am. Chem. Soc., 139, 11519-11526 (2017).

2015

  1. "Synthesis of a Stable Selenoaldehyde (RCH=Se) by Self-Catalyzed Thermal Dehydration of a Primary-Alkyl-Substituted Selenenic Acid (RCH2SeOH)", S. Sase, R. Kakimoto, and K. Goto, Angew. Chem., Int. Ed., 54, 901-904 (2015) (selected as Inside Cover).
  2. "Oxygen-Atom-Transfer Reactions of a Pd(II) Peroxocarbonate Complex", S. Sase, M. Hashimoto, and K. Goto, Chem. Lett., 44, 157-159 (2015).
  3. "Synthesis, Structure, and Reactivities of a Stable Primary-Alkyl-Substituted Sulfenic Acid", M. Ishihara, N. Abe, S. Sase, and K. Goto, Chem. Lett., 44, 615-617 (2015).
  4. "Generation, Characterization, and Reactivity of a CuII-alkylperoxide/anilino-radical Complex: Insight into the O-O Bond Cleavage Mechanism", S. Paria, T. Ohta, U. Morimoto, T. Ogura, H. Sugimoto, N. Fujieda, K. Goto, T. Suzuki, and S. Itoh, J. Am. Chem. Soc., 137, 10870-10873 (2015).
  5. "Synthesis of a Stable Primary-Alkyl-Substituted Selenenyl Iodide and Its Hydrolytic Conversion to the Corresponding Selenenic Acid", S. Sase, R. Kakimoto, R. Kimura, and K. Goto, Molecules, 20, 21415-21420 (2015).

2014

  1. "Efficient End-Capping Synthesis of Neutral Donor-Acceptor [2]Rotaxanes under Additive-Free and Mild Conditions", Y. Domoto, S. Sase, and K. Goto, Chem. - Eur. J., 20, 15998-16005 (2014).
  2. "Chloro-(η6-p-cymene)-{3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2"6"-tetramethyl-1,1':3',1"-terphenyl-5'-yl)imidazol-2-ylidene}-ruthenium(II) benzene disolvate", S. Sase, Y. Ikehara, and K. Goto, Acta Crystallogr., Sect. E, 70, m394 (2014).
  3. "Synergy of Reactivity and Stability in Nanoscale Molecular Architectures", K. Goto, In Synergy in Supramolecular Chemistry; T. Nabeshima, Ed.; CRC Press: London, 2014; pp 191-218.

2013

  1. "Transnitrosation from a stable thionitrate to an amine with concomitant formation of a sulfenic acid", K. Goto, S. Yoshikawa, T. Ideue, and S. Sase, J. Sulfur Chem., 34, 705-710 (2013).

2012

  1. "Iodide-Promoted Deselenylation of β-Chloro- and β-Oxyselenides to Form Alkenes and Selenenyl Iodides", S. Sase, K. Ebisawa, and K. Goto, Chem. Lett., 41, 766-768 (2012).
  2. "Copper(I)-Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand: Formation and Reactivity of a Mononuclear Copper(II) End-On Superoxo Complex", Y. Kobayashi, K. Ohkubo, T. Nomura, M. Kubo, N. Fujieda, H. Sugimoto, S. Fukuzumi, K. Goto, T. Ogura, and S. Itoh, Eur. J. Inorg. Chem., 2012, 4574.

2011

  1. "Formation of a Unique Fluorosilene-KF Complex Bearing Bulky Substituents", E. Mieda, T. Sasamori, S. Sase, K. Goto, and N. Tokitoh, Chem. Lett., 40, 196-197 (2011).
  2. "Syntheses of Biologically-relevant Reactive Sulfur Species by Utilizing a Primary Alkyl Steric Protection Group", S. Sase, Y. Aoki, N. Abe, and K. Goto, Phosphorus, Sulfur Silicon Relat. Elem., 186, 1255-1258 (2011).
  3. 分子キャビティを活用した含ヨウ素高反応性中間体の安定化, 後藤 敬, SIS Lett., 12, 2-11 (2011).
  4. 分子のボウルを使って生体反応活性種をモデル化する, 後藤 敬, 化学と教育, 59, 604-605 (2011).

2010

  1. "Modeling of the 5'-Deiodination of Thyroxine by Iodothyronine Deiodinase: Chemical Corroboration of a Selenenyl Iodide Intermediate", K. Goto, D. Sonoda, K. Shimada, S. Sase, and T. Kawashima, Angew. Chem., Int. Ed., 49, 545-547 (2010).
  2. "5,6,7,12-Tetrahydro-6-(1-methylethyl)-12-phenyldibenz[c,f][1,5]azasilocine" K. Goto, A. Fukushima, and T. Kawashima, Acta Crystallogr., Sect. E, 66, o20 (2010) (selected as cover illustration).
  3. "Photo- and Thermal Isomerization of Shuttlecock- and Bowl-Equipped Phenylazopyridines", K. Suwa, J. Otsuki, and K. Goto, J. Phys. Chem. A, 114, 884-890 (2010).
  4. "Synthesis and Properties of Pentacoordinated Phenoxysilane and Carboxysilanes with Intramolecular Nitrogen-Silicon Coordination", Y. Domoto, K. Saruhashi, A. Fukushima, S. Sase, K. Goto, and T. Kawashima, Phosphorus, Sulfur Silicon Relat. Elem., 185, 1221-1229 (2010).
  5. "Catalyst-free Syntheses of [2]Rotaxanes Utilizing a Pentacoordinated Hydrosilane as an End-capping Agent", Y. Domoto, A. Fukushima, Y. Kasuga, S. Sase, K. Goto, and T. Kawashima, Org. Lett., 12, 2586-2589 (2010).

2009

  1. "Syntheses of Shuttlecock- and Bowl-Equipped Phenylazopyridines and Photomodulation of Their Coordination Ability to Zn-porphyrin", K. Suwa, J. Otsuki, and K. Goto, Tetrahedron Lett., 50, 2106-2108 (2009).
  2. "Synthesis and Structural Characterization of a Mixed Aggregate Containing a Lithium Thiolate and a Lithium Amide", K. Goto, Y. Takahashi, and T. Kawashima, J. Sulfur Chem., 30, 365-369 (2009).
  3. 新規な立体保護基の開発と生体反応活性種安定化への応用, 後藤 敬, ファインケミカル, 38, 27-36 (2009).
  4. "Stable Sulfenyl Iodide Bearing a Primary Alkyl Steric Protection Group with a Cavity-shaped Framework", S. Sase, Y. Aoki, N. Abe, and K. Goto, Chem. Lett., 38, 1188-1189 (2009).

2008

  1. "Chemistry of Calixfurans", K. Goto, Top. Heterocycl. Chem., 17, 97-121 (2008).

2007

  1. "Syntheses and Characterization of Alkylzirconium Complexes Containing Two Silanolato Ligands with a Bowl-shaped Framework", I. Shimo, T. Okumura, K. Goto, and T. Kawashima, J. Organomet. Chem., 692, 2115-2119 (2007).
  2. "Synthesis and Crystal Structure of a Zirconium Complex Containing Germanolato Ligands and Its Catalytic Activity for Ethylene Polymerization", K. Goto, I. Shimo, T. Okumura, and T. Kawashima, Chem. Lett., 36, 776-777 (2007).

2006

  1. "Reactivity of 1-Hydro-5-carbaphosphatrane Based on Tautomerization between Pentavalent Phosphorane and Trivalent Cyclic Phosphonite", J. Kobayashi, K. Goto, T. Kawashima, M. W. Schmidt, and S. Nagase, Chem. Eur. J., 12, 3811-3820 (2006).
  2. "Shuttlecock-like Arrangement of a Tweezer-type Cavitand in the Crystalline State", A. Yoshida, K. Goto, and T. Kawashima, Bull. Chem. Soc. Jpn., 79, 793-795 (2006).
  3. "Formation of a Stable Sulfenic Acid by Hydrolysis of a Thionitrate and a Sulfenyl Bromide" K. Goto, K. Shimada, S. Furukawa, S. Miysasaka, Y. Takahashi, and T. Kawashima, Chem. Lett., 35, 862-863 (2006).

2005

  1. "Fixation of Both O2 and CO2 from Air by a Crystalline Palladium Complex Bearing N-Heterocyclic Carbene Ligands", M. Yamashita, K. Goto, and T. Kawashima, J. Am. Chem. Soc., 127, 7294-7295 (2005).
  2. "Theoretical Evidence for Enhanced NO Dimerization in Aromatic Hosts: Implications for the Role of the Electrophile (NO)2 in Nitric Oxide Chemistry", Y.-L. Zhao, M. D. Bartberger, K. Goto, K. Shimada, T. Kawashima, and K. N. Houk, J. Am. Chem. Soc., 127, 7964-7965 (2005).
  3. "Syntheses, Structures, and Properties of Quinone-Bridged Calix[6]arenes", S. Akine, K. Goto, and T. Kawashima, Bull. Chem. Soc. Jpn., 78, 167-179 (2005).
  4. "Thermolysis and Photolysis of Stable Se-Nitrososelenols" K. Shimada, K. Goto, and T. Kawashima, Chem. Lett., 34, 654-655 (2005).
  5. "Syntheses of the First Se-Nitrososelenol and Related Compounds", K. Goto, K. Shimada, and T. Kawashima, Phosphorus, Sulfur Silicon Relat. Elem., 180, 945-949 (2005).
  6. "Syntheses and Structures of Bowl-shaped Triarylphosphines and Their Palladium(II) Complexes", Y. Ohzu, K. Goto, H. Sato, and T. Kawashima, J. Organomet. Chem., 690, 4175-4183 (2005).
  7. "Nanoscale Molecular Cavities for Stabilization of Highly Reactive Species", K. Goto and T. Kawashima, J. Synth. Org. Chem., Jpn., 63, 1157-1170 (2005) (Special Issue in English).

2004

  1. "Isolation of A Se-nitrososelenol: A New Class of Reactive Nitrogen Species Relevant to Protein Se-Nitrosation", K. Shimada, K. Goto, T. Kawashima, N. Takagi, Y.-K. Choe, and S. Nagase, J. Am. Chem. Soc., 126, 13238-13239 (2004).

2003

  1. "A Novel Bowl-shaped Triarylphosphane with a Large Cone Angle: Synthesis and Crystallographic Analysis of the First [(PdX2)3(PR3)2]-type Complex", Y. Ohzu, K. Goto, and T. Kawashima, Angew. Chem., Int. Ed., 42, 5714-5717 (2003).
  2. "Syntheses and Structural Characterizations of a Novel Bowl-type Germanol and Its Derivatives", K. Goto, I. Shimo, and T. Kawashima, Bull. Chem. Soc. Jpn., 76, 2389-2394 (2003).
  3. "Reaction of Stable Sulfenic and Selenenic Acids Containing a Bowl-type Steric Protection Group with a Phosphine. Elucidation of the Mechanism of Reduction of Sulfenic and Selenenic Acids", K. Goto, K. Shimada, M. Nagahama, R. Okazaki, and T. Kawashima, Chem. Lett., 2003, 1080-1081.
  4. "Isolation and structural analysis of novel conformational isomers of the m-xylylene-bridged calix[6]arenes: the "partial cone" and "inverted cone" isomers", S. Akine, K. Goto, and T. Kawashima, Tetrahedron Lett., 177, 2037-2038 (2003).

2002

  1. "Synthesis, Structure and Bonding Properties of 5-Carbaphophatranes: A New Class of Main Group Atrane", J. Kobayashi, K. Goto, T. Kawashima, M. W. Schmidt, and S. Nagase, J. Am. Chem. Soc, 124, 3703-3712 (2002).
  2. "Synthesis of Highly Reactive Organosulfur Compounds", R. Okazaki and K. Goto, Heteroatom Chem., 13, 414-418 (2002).
  3. "Synthesis of Novel Triarylphosphines Bearing a m-Terphenyl-based Dendrimer-type Framework", K. Goto, Y. Ohzu, and T. Kawashima, Phosphorus, Sulfur Silicon Relat. Elem.,177, 1405-1407 (2002).
  4. "Bonding Properties of 5-Carbaphosphatranes", K. Goto, J. Kobayashi, T. Kawashima, M. W. Schmidt, and S. Nagase, Phosphorus, Sulfur Silicon Relat. Elem., 177, 2037-2038 (2002).
  5. "Reactions of 1-Hydro-5-Carbaphosphatrane: Tautomerization between Five Coordinate and Three Coordinate Species", J. Kobayashi, K. Goto, and T. Kawashima, Phosphorus, Sulfur Silicon Relat. Elem., 177, 1405-1407 (2002).

2001

  1. "The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid: Experimental Demonstration of Three Processes Included in the Catalytic Cycle of Glutathione Peroxidase", K. Goto, M. Nagahama, T. Mizushima, K. Shimada, T. Kawashima, and R. Okazaki, Org. Lett., 2001, 3569.
  2. "5-Carbaphosphatranes: The First Main Group Atrane Bearing a 1-5 Covalent Bond", J. Kobayashi, K. Goto, and T. Kawashima, J. Am. Chem. Soc., 123, 3387-3388 (2001).
  3. "Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-type Steric Protection Group", K. Goto, Y. Hino, Y. Takahashi, T. Kawashima, G. Yamamoto, N. Takagi, and S. Nagase, Chem. Lett., 2001, 1204.
  4. "Synthesis, Structure, and Reactions of a Novel Triarylsilanol with a Bowl-type Framework: A Silanol Extremely Resistant to Self-condensation", K. Goto, T. Okumura, and T. Kawashima, Chem. Lett., 2001, 1258.
  5. "A Novel Dendrimer-Type m-Terphenyl Substituent for the Kinetic Stabilization of Highly Reactive Species", K. Goto, G. Yamamoto, B. Tan, and R. Okazaki, Tetrahedron Lett., 42, 4875-4877 (2001).
  6. "Structural Characterization of a Pentacoordinate Monohydrosilane with the Apical Si-H Bond", K. Saruhashi, K. Goto, and T. Kawashima, Chem. Heterocycl. Compd., 37,1394-1395 (2001).
  7. "Synthesis and Structure of 5-Carbaphosphatrane", J. Kobayashi, K. Goto, and T. Kawashima, Phosphorus, Sulfur Silicon Relat. Elem., 168, 597-600 (2001).
  8. "Conformational Mobility of the Bridged Calix[6]arenes with Allyl and Ethyl Groups at the Lower Rim", S. Akine, K. Goto, and T. Kawashima, Bull. Chem. Soc. Jpn., 74, 2167-2174 (2001).
  9. "Synthesis and Reactions of Conformational Isomers of a Stable Selenenic Acid Bearing a Bridged Calix[6]arene Framework", K. Goto, T. Saiki, S. Akine, T. Kawashima, and R. Okazaki, Heteroatom Chem., 12, 195-197 (2001).

2000

  1. "Synthesis and Crystal Structure of a Stable S-Nitrosothiol Bearing a Novel Steric Protection Group and of the Corresponding S-Nitrothiol", K. Goto, Y. Hino, T. Kawashima, M. Kaminaga, E. Yano, G. Yamamoto, N. Takagi, and S. Nagase, Tetrahedron Lett., 41, 8479-8483 (2000).
  2. "Synthesis, Structure, and Redox Properties of a Quinone-Bridged Calix[6]arene", S. Akine, K. Goto, and T. Kawashima, Tetrahedron Lett., 41, 897-901 (2000).
  3. "Crystal Structures and Solvate Formation of Two Conformationally Frozen Isomers of a Bridged Calix[6]arene", S. Akine, K. Goto, and T. Kawashima, J. Inclusion Phenomena and Macrocyclic Chem., 36, 117-122 (2000).
  4. "Structural Elucidation of 1,3-Phenylenebis(methylene)-bridged Calix[6]arenes with Four Uncapped Hydroxy Groups", T. Saiki, S. Akine, K. Goto, N. Tokitoh, T. Kawashima, and R. Okazaki, Bull. Chem. Soc. Jpn., 73, 1893-1902 (2000).
  5. "Syntheses and Structures of Novel m-Xylylene-bridged Calix[6]arenes: Stabilization of a Sulfenic Acid in the Cavity of Calix[6]arene", T. Saiki, K. Goto, N. Tokitoh, M. Goto, and R. Okazaki, J. Organomet. Chem., 611, 146-157 (2000).

1999

  1. "Different Aggregating Properties of Two Conformationally Frozen Isomers of a Water-Soluble Bridged Calix[6]arene", S. Akine, K. Goto, T. Kawashima, and R. Okazaki, Bull. Chem. Soc. Jpn., 72, 2781-2783 (1999).
  2. "Desilylation-triggered Isomerization of a Molecular Capsule from an Open-type to a Collapsed-type Isomer", S. Watanabe, K. Goto, T. Kawashima, and R. Okazaki, Tetrahedron Lett., 40, 3569-3572 (1999).
  3. "Syntheses and Structures of Stable Sulfenyl Iodides Bearing Novel Bowl-type and Dendrimer-type Substituents", K. Goto, M. Holler, G. Yamamoto, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 153, 313-314 (1999).
  4. "Micropolarity around a Zwitterionic Solvatochrome Covalently Fixed in the Cavity of Bowl-shaped Cyclophanes", S. Akine, K. Goto, and R. Okazaki, Chem. Lett., 1999, 681-682.
  5. "Synthesis, Structure, and Reducing Ability of a Stable Organotrihydroaluminate Bearing a Novel Bowl-type Substituent", K. Goto, J. Kobayashi, and R. Okazaki, Organometallics, 18, 1357-1359 (1999).
  6. 分子のお椀と提灯の化学−新しい分子空孔の設計と高反応性化学種安定化への応用(化学のフロンティア '99), 後藤 敬, 化学と工業, 52, 155 (1999).
  7. 高反応性化学種の反応容器としての巨大分子, 後藤 敬, 岡崎廉治, 化学と工業, 52, 972 (1999).

1998

  1. "Novel Intramolecular Cyclization Reaction Involving a Thionitroso Group: Formation of a 3,3a-dihydro-2,1-benzisothiazole from an o-alkylthionitrosoarene" B. Tan, K. Goto, J. Kobayashi, and R. Okazaki. Chem. Lett., 1998, 981-982.
  2. "Synthesis and Crystal Structure of an Arenesulfenyl Iodide with Unprecedented Stability", K. Goto, M. Holler, and R. Okazaki, Chem. Commun., 1998, 1915-1916.
  3. "Synthesis of Novel Water-soluble Molecular Bowls and Their Unique Complexing Behavior with 1-Anilinonaphthalene-8-Sulfonate", K. Goto, S. Akine, T. Hayashi, and R. Okazaki, Chem. Lett., 1998, 291-292.
  4. "Synthesis, Structure, and Reactions of Stable Selenenic Acids Bearing Novel Bridged Calix[6]arene Frameworks", K. Goto, T. Saiki, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 136-138, 475-478 (1998).

1997

  1. "Synthesis, Structure, and Reactions of a Sulfenic Acid Bearing a Novel Bowl-type Substituent: The First Synthesis of a Stable Sulfenic Acid by Direct Oxidation of a Thiol", K. Goto, M. Holler, and R. Okazaki, J. Am. Chem. Soc., 119, 1460-1461 (1997).
  2. "An Endohedral Simple Enol: The First Isolation of a b-Unsubstituted Simple Enol Utilizing a Lantern-shaped Molecular Framework", S. Watanabe, K. Goto, T. Kawashima, and R. Okazaki, J. Am. Chem. Soc., 119, 3195-3196 (1997).
  3. "Isolation and X-ray Crystallographic Analysis of a Stable Selenenic Acid", T. Saiki, K. Goto, and R. Okazaki, Angew Chem. Int. Ed. Engl., 36, 2223-2224 (1997).
  4. "Molecular Bowls and Capsules with an Endohedral Functionality: The Stabilization of Highly Reactive Species in Their Inner Phase", K. Goto and R. Okazaki, Liebigs Ann./Recl., 1997, 2393-2407.
  5. "Synthesis of a Stable Sulfenic Acid by Oxidation of a Thiol Bearing a Novel Bowl-type Substituent and Its Redox Reactions", K. Goto, M. Holler, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 120, 325-326 (1997).

Books and Others

  1. 化合物の辞典,後藤 敬(分担執筆),高木 進,稲本直樹,中原勝儼,山崎 昶編,朝倉書店 (1997).
  2. 化学便覧基礎編改訂5版,川島隆幸,後藤 敬(分担執筆),日本化学会編,丸善 (2004).
  3. 安定なジオキサホスフィラン, 後藤 敬, Organometallic News, 2004, 55.
  4. 分子の「輪」で「軸」を保護する−ロタキサン構造を利用した蛍光色素の超分子的立体保護−, 後藤 敬, 化学, 60, 64 (2005).
  5. ゲルマノンの単離を可能にした分子設計, 後藤 敬, Organometallic News, 2012, 66.
  6. 理科年表,後藤 敬(分担執筆),国立天文台編,丸善 (2014).
  7. 現代有機硫黄化学〜基礎から応用まで,後藤 敬(分担執筆),高田十志和,村井利昭,小川 智,佐藤総一編,化学同人(2014).
  8. 発展する有機セレン化学−典型元素触媒としての応用, 佐瀬 祥平,後藤 敬, 化学, 71, 70 (2016).
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