Intermetallic Compound Catalyst

  1. "Correlation Between Activation Energy and the Electronic State of Pd-based Bimetallic Catalysts for H2–D2 Equilibration Obtained by XPS and DFT Calculations"
    M. Miyazaki, S. Furukawa and T. Komatsu, Bull. Chem. Soc. Japan, 93, 1020-1025 (2020).
    DOI: 10.1246/bcsj.20200085
  2. "Surface Modification of PdZn Nanoparticles via Galvanic Replacement for the Selective Hydrogenation of Terminal Alkynes"
    M. Miyazaki, S. Furukawa, T. Takayama, S. Yamazoe and T. Komatsu, ACS Appl. Nano Mater., 2, 3307-3314 (2019).
    DOI: 10.1021/acsanm.9b00761
  3. "Highly Active Ni- and Co-based bimetallic Catalysts for Hydrogen Production from Ammonia-Borane"
    S. Furukawa, G. Nishimura, T. Takayama, T. Komatsu, Front. Chem., 7, 138-144 (2019).
    DOI: 10.3389/fchem.2019.00138
  4. "Au–Ag Nanoflower Catalysts with Clean Surfaces for Alcohol Oxidation"
    Y. Imura, R. Akiyama, S. Furukawa, R. Kan, C. Morita‐Imura, T. Komatsu, T. Kawai, Chem. Asian J., 14, 547-552 (2019).
    DOI: 10.1002/asia.201801711
  5. "Remarkable Enhancement in Hydrogenation Ability by Phosphidation of Ruthenium: Specific Surface Structure Having Unique Ru Ensembles"
    S. Furukawa, Y. Matsunami, I. Hamada, Y. Hashimoto, Y. Sato, and T. Komatsu, in press
    DOI: 10.1021/acscatal.8b02582
  6. "Regio- and Chemoselective Hydrogenation of Dienes to Monoenes Governed by a Well-Structured Bimetallic Surface"
    M. Miyazaki, S. Furukawa, T. Komatsu, in press
    DOI: 10.1021/jacs.7b08792
  7. "Selective Activation of Alcohols in the Presence of Reactive Amines over Intermetallic PdZn: Efficient Catalysis for Alcohol-Based N-Alkylation of Various Amines"
    S. Furukawa, R. Suzuki and T. Komatsu, ACS Catal., 6, 5946-5953 (2016)
    DOI: 10.1021/acscatal.6b01677 "selected for the front cover"
  8. "Oxygen Sensitivity of Intermetallic Compound Surface Comprising Early Transition Metal"
    S. Furukawa, G. Nishimura, T. Komatsu, J. Jpn. Petrol. Inst., 59, 160-163 (2016).
    DOI: 10.1627/jpi.59.160
  9. "Well-structured Bimetallic Surface Capable of Molecular Recognition for Chemoselective Nitroarene Hydrogenation"
    S. Furukawa, K. Takahashi and T. Komatsu, Chem. Sci., 7, 4476-4484 (2016).
    DOI: 10.1039/C6SC00817H
    "Highlighted in Synfacts, 2016, 12, 0987."
  10. "Surface clean gold nanoflower obtained by complete removal of capping agents: an active catalyst for alcohol oxidation"
    Y. Imura, S. Furukawa, K. Ozawa, C. Morita-Imura, T. Kawai and T. Komatsu, RSC Adv., 6, 17222-17227 (2016).
    DOI: 10.1039/C5RA27146K
  11. "Selective Hydrogenation of Functionalized Alkynes to (E)-Alkenes Using Ordered Alloys as Catalysts"
    S. Furukawa and T. Komatsu, ACS Catal., 6, 2121-2125 (2016).
    DOI: 10.1021/acscatal.5b02953
  12. "Efficient Catalytic System for Chemoselective Hydrogenation of Halonitrobenzene to Haloaniline Using PtZn Intermetallic Compound"
    S. Iihama, S. Furukawa and T. Komatsu, ACS Catal., 6, 724-726 (2016).
    DOI: 10.1021/acscatal.5b02464
    Highlighted in Synfacts, 2016, 12, 0656."
  13. "Raney-Type Ru-La Catalysts Prepared from a Ru-La-Al Ternary Alloy: Enhanced Activity in Ammonia Decomposition"
    S. Furukawa, A. Tsuchiya, Y. Kojima, M. Endo and T. Komatsu, Chem. Lett., 45(2), 158-160 (2016).
    DOI: 10.1246/cl.151036
  14. "Unique Reaction Mechanism of Preferential Oxidation of CO over Intermetallic Pt3Co Catalysts: Surface-OH-Mediated Formation of Bicarbonate Intermediate"
    S. Furukawa, K. Ehara and T. Komatsu, Catal. Sci. Technol., 6, 1642-1650 (2016).
    DOI: 10.1039/C5CY01652E "selected for the back cover"
  15. "Selective Stereochemical Catalysis Controlled by Specific Atomic Arrangement of Ordered Alloys"
    S. Furukawa, K. Ochi, H. Luo, M. Miyazaki, T. Komatsu, ChemCatChem, 7, 3472 – 3479 (2015).
    DOI: 10.1002/cctc.201500808 "selected for the inside front cover"
  16. "Hydrogen Production from Aqueous Solutions of Urea with Ruthenium-based Catalysts"
    S. Furukawa, R. Suzuki, K. Ochi, T. Yashima, T. Komatsu, ChemSusChem, 8, 2028 – 2030 (2015).
    DOI: 10.1002/cssc.201500112 "selected for the front cover"
  17. "Mechanistic Study on Aerobic Oxidation of Amine over Intermetallic Pd3Pb: Concerted Promotion Effects by Pb and Support Basicity"
    S. Furukawa, A. Suga and T. Komatsu, ACS Catal., 5, 1214 – 1222 (2015).
    DOI: 10.1021/cs501695m
  18. "Efficient Catalytic System for Synthesis of Trans-Stilbene from Diphenylacetylene Using Rh-Based Intermetallic Compounds"
    S. Furukawa, A. Yokoyama and T. Komatsu, ACS Catal., 4, 3581 – 3585 (2014).
    DOI: 10.1021/cs500947d
  19. "Bifunctional Catalytic System Effective for Oxidative Dehydrogenation of 1-Butene and n-Butane Using Pd-Based Intermetallic Compounds"
    S. Furukawa, M. Endo and T. Komatsu, ACS Catal., 4, 3533 – 3542 (2014).
    DOI: 10.1021/cs500920p
  20. "Study on the Hydrogen Activation Properties of Ni-Based Intermetallics: Relationship between Reactivity and Electronic State"
    S. Furukawa, K. Ehara, K. Ozawa and T. Komatsu, Phys. Chem. Chem. Phys., 16, 19828-19831 (2014).
    DOI: 10.1039/C4CP01514B
    "selected for the back cover"
  21. "Chemoselective Hydrogenation of Nitrostyrene to Aminostyrene over Pd- and Rh-based Intermetallic Compounds"
    S. Furukawa, Y. Yoshida and T. Komatsu, ACS Catal., 4, 1441 - 1450 (2014).
    DOI: 10.1021/cs500082g
    "Highlighted in Organic Chemistry Portal."
  22. "Highly Efficient Aerobic Oxidation of Various Amines Using Pd3Pb Intermetallic Compounds as Catalysts"
    S. Furukawa, A. Suga and T. Komatsu, Chem. Commun., 50, 3277 - 3280 (2014).
    DOI: 10.1039/C4CC00024B
    "selected for the journal cover"
    "Highlighted in Synfacts, 2014, 10, 0660."
  23. "Catalytic Properties of Pt-based Intermetallic Compounds in dehydrogenation of cyclohexane and n-butane"
    S. Furukawa, A. Tamura, K. Ozawa and T. Komatsu, Appl. Catal. A: Gen., 469, 300 - 305 (2014).
    DOI: 10.1016/j.apcata.2013.10.012
  24. "Preparation of Alumina-Supported Intermetallic Compounds"
    S. Furukawa, K. Ozawa and T. Komatsu, RSC Adv., 3, 23269 - 23277 (2013).
    DOI: 10.1039/C3RA43163K
  25. "PtCu Intermetallic Compound Supported on Alumina Active for Preferential Oxidation of CO in Hydrogen"
    T. Komatsu, M. Takasaki, K. Ozawa, S. Furukawa and A. Muramatsu, J. Phys. Chem. C, 117, 10483 - 10491 (2013).
    DOI: 10.1021/jp4007729
  26. "Synthesis of trans-stilbene through the hydrogenation of diphenylacetylene"
    T. Komatsu, K. Takagi and K. Ozawa, Catal. Today, 164, 143 - 147 (2011).
    DOI: 10.1016/j.cattod.2010.10.089
  27. "Preparation and catalytic properties of fine particles of Pt-Ge intermetallic compound formed inside the mesopores of MCM-41"
    T. Komatsu, K. Sou and K. Ozawa, J. Mol. Catal. A: Chemical, 319, 71 - 77 (2010).
    DOI: 10.1016/j.molcata.2009.12.002
  28. "Ru-Ti intermetallic catalysts for the selective hydrogenation of crotonaldehyde"
    J. Ruiz-Martinez, Y. Fukui, T. Komatsu and A. Sepulveda-Escribano, J. Catal., 260(1), 150 - 156 (2008).
    DOI: 10.1016/j.jcat.2008.09.024
  29. "Selective hydrogenation of acetylene into ethylene on fine particles of Pd3Bi intermetallic compound supported on silica"
    T. Komatsu and T. Gorai, Abst. 14th Intern. Congr. Catal., OB31 (Seoul, 2008) p. 69.
    DOI: N/A
  30. "Preparation and catalytic properties of uniform particles of Ni3Ge intermetallic compound formed inside the mesopores of MCM-41"
    T. Komatsu, T. Kishi and T. Gorai, J. Catal., 259(2), 174 - 182 (2008).
    DOI: 10.1016/j.jcat.2008.08.001
  31. "Pt3Co and PtCu intermetallic compounds: Promising catalysts for preferential oxidation of CO in excess hydrogen"
    T. Komatsu and A. Tamura, J. Catal., 258(2), 306 - 314 (2008).
    DOI: 10.1016/j.jcat.2008.06.030
  32. "Dehydroisomerization of butane into isobutene on Pt-Sn intermetallic compounds supported on H-SAPO-11"
    T. Komatsu and H. Ikenaga, J. Catal., 241(2), 426 - 434 (2006).
    DOI: 10.1016/j.jcat.2006.05.018
  33. "CO2 reforming of methane on Ni- and Co-based intermetallic compound catalysts"
    T. Komatsu and T. Uezono, J. Jpn. Petrol. Inst., 48(2), 76 - 83 (2005).
    DOI: 10.1627/jpi.48.76
  34. "Fischer-Tropsch synthesis on RuTi intermetallic compound catalyst"
    T. Komatsu and Y. Fukui, Appl. Catal. A: General, 279, 173 - 180 (2005).
    DOI: 10.1016/j.apcata.2004.10.028
  35. "Characterizations and catalytic properties of fine particles of Ni-Sn intermetallic compounds supported on SiO2"
    A. Onda, T. Komatsu and T. Yashima, J. Catal., 221, 378 - 385 (2004).
    DOI: 10.1016/j.jcat.2003.08.012
  36. "Nano-size particles of palladium intermetallic compounds as catalysts for oxidative acetoxylation"
    T. Komatsu, K. Inaba, T. Uezono, A. Onda and T. Yashima, Appl. Catal. A: General, 251, 315 - 326 (2003).
    DOI: 10.1016/S0926-860X(03)00380-6
  37. "Preparation and catalytic properties of single-phase Ni-Sn intermetallic compound particles by CVD of Sn(CH3)4 onto Ni/silica"
    A. Onda, T. Komatsu and T. Yashima, J. Catal., 201, 13 - 21 (2001).
    DOI: 10.1006/jcat.2001.3231
  38. "Ti-Pt intermetallic compound catalysts more active than Pt for hydrogen dissociation and ethylene hydrogenation"
    T. Komatsu, D. Satoh and A. Onda, Chem. Commun., No. 12, 1080 - 1081 (2001).
    DOI: 10.1039/B102415A

Zeolite Catalyst

  1. "Factors affecting coke formation on H-ZSM-5 in naphtha cracking"
    R. Javaida, K. Urata, S. Furukawa and T. Komatsu, Appl. Catal. A: General, 491, 100 - 105 (2015).
    DOI: 10.1016/j.apcata.2014.12.002
  2. "Location of coke on H-ZSM-5 zeolite formed in the cracking of n-hexane"
    K. Urata, S. Furukawa and T. Komatsu, Appl. Catal. A: General, 475, 335 - 340 (2014).
    DOI: 10.1016/j.apcata.2014.01.050
  3. "Ca2+-exchanged ferrierite: quasi one-dimensional zeolite for highly selective and stable formation of light alkenes in catalytic cracking of n-octane"
    L. Wang, K. Ozawa, T. Komatsu and T. Ikeda, Appl. Catal. A: General, 407, 127 - 133 (2011).
    DOI: 10.1016/j.apcata.2011.08.028
  4. "Catalytic combustion of dioxin analogue compounds on Pt supported zeolite"
    T. Komatsu and R. Ooshima, J. Jpn Petrol. Inst., 52(6), 332 - 340 (2009).
    DOI: 10.1627/jpi.52.332
  5. "Crystallization of zeolite beta in the presence of chiral amine or rhodium complex"
    Y. Takagi, T. Komatsu and Y. Kitabata, Micropor. Mesopor. Mater., 109(1-3), 567 - 576 (2008).
    DOI: 10.1016/j.micromeso.2007.06.005
  6. "Cu-loaded dealuminated Y zeolites active in selective catalytic reduction of nitric oxide with ammonia"
    T. Komatsu, T. Nagai and T. Yashima, Res. Chem. Intermed., 32(3-4), 291 - 304 (2006).
    DOI: 10.1163/156856706777346417
  7. "Gas phase synthesis of para-aminophenol from nitrobenzene on Pt/zeolite catalysts"
    T. Komatsu, T. Hirose, Appl. Catal. A: General, 276, 95 - 102 (2004).
    DOI: 10.1016/j.apcata.2004.07.044
  8. "Aldol condensation catalyzed by acidic zeolites"
    T. Komatsu, M. Mitsuhashi and T. Yashima, Stud. Surf. Sci. Catal., 142, 667 - 674 (2002).
    DOI: 10.1016/S0167-2991(02)80087-8
  9. "Selective formation of alkenes through the cracking of n-heptane on Ca2+-exchanged ferrierite"
    T. Komatsu, H. Ishihara, Y. Fukui and T. Yashima, Appl. Catal. A, General, 214, 103 - 109 (2001).
    DOI: 10.1016/S0926-860X(01)00466-5


  1. "Intermetallic Compounds: Promising Inorganic Materials for Well-Structured and Electronically Modified Reaction Environments for Efficient Catalysis"
    S. Furukawa and T. Komatsu, ACS Catal., 7, 735-765 (2017).
    DOI: 10.1021/acscatal.6b02603
  2. "Catalytic properties of single-phase intermetallic compounds"
    T. Komatsu and A. Onda, Catalysis Surveys from Asia, Springer Netherlands, 12, 6 - 15 (2008).
    DOI: 10.1007/s10563-007-9031-3
  3. 「単一相金属間化合物触媒の調製とその触媒特性の解明」
    小松, 恩田, 触媒, 53(1), 38 - 43 (2011).
    DOI: N/A
  4. "Intermetallic Compound Nanoparticles Dispersed on the Surface of Oxide Support as Active and Selective Catalysts"
    T. Komatsu and S. Furukawa, Mater. Trans., 56(4), 460 – 467 (2015).
    DOI: 10.2320/matertrans.MF201408


  1. 公開番号:特開2003-340285号
  2. 公開番号:特開2004-167387号
  3. 公開番号:特開2003-55274号
  4. 特許番号:特許第6621016号