Welcome to the Toyota laboratory!

 "Physical Organic Chemistry" is chemical research area in which we study structure, properties, and reactivity of organic compounds precisely in order to disclose new principles and theories for the relationships between molecular structures and their properties. Based on the idea, we design and synthesize novel organic compounds with unique structure, and we investigate their structure and chemical properties by spectroscopic measurements and theoretical approach.
 Recently, we focus on development of novel "simple yet elegant" π electronic units and we apply them to construct functional 2D or 3D organic architectures. Our research policy is "Design new molecule outside the box, Make the molecule, and Study to find charmy aspects of the molecule".

 We are now recruiting undergraduates, graduated students, and post-Docs. Feel free to contact us if you intend to take a look into our laboratory. Link to address page

News

2019.4.9 Four new Members joined our laboratory.
2019.7.21-26 We attended the 18th International Symposium on Novel Aromatic Compounds (ISNA-18) and gave presentations.
2019.7.2 New paper has been published in Bulltin of the Chemical Society of Japan.
2019.4.2 Six new Members joined our laboratory.
2019.4.1 Dr. Masahiro Yamashina joined our laboratory as an Assistant Professor. Members
2019.3.19 New paper has been published in Teterahedron Letters.
2019.3.26 Dr. Yuta Yamamoto, M.D. Hiroshi Sekikawa, M.D. Masahiko Kawamura were graduated. Congratulations!
2019.3.16-19 We attended The 99th CSJ Annual Meeting and gave presentations.Details
2019.2.18 We contributed an interpretive article on Nano-Saturns in Gekkan Kagaku (Kagaku Doujin) vol.2019-03. Link
2019.1.28 New review has been published in Chemistry A European Journal.
2018.12.4 ”Nano-Saturn” was nominated for Molecules of the year 2018 (by C&E News). Link
2018.12.1 New paper has been published in Chemistry Letters.
2018.11.30-12.1 We attended 12th Symposium on Organic π Electronic Systems and gave poster presentations.

Recent Papers


"Nano-Saturn with an Ellipsoidal Body: Anthracene Macrocyclic Ring-C70 Complex."
S. Toyota, Y. Yamamoto, Kan Wakamatsu, E. Tsurumaki, A. Muñoz-Castro,
Bull. Chem. Soc. Jpn., 2019, 92, 1721-1728. Abstract

This article was awarded as "Selected Paper".


"Synthesis and photophysical properties of dinaphtho[2,3-b:2',3'-i]dihydrophenazine derivatives"
T. Iwanaga, N. Asano, H. Yamada, S. Toyota,
Tetrahedron Lett., 2019, 60, 1113-1116. Abstract


"Exploration of Nano-Saturns: A Spectacular Sphere-Ring Supramolecular System."
S. Toyota, E. Tsurumaki,
Chem. Eur. J., 2019, 25, 6878-6890. Abstract


"Box-Shaped Cyclic Oligoarenes: Synthesis and Structure of Anthracene-1,8-diyl Cyclic Tetramers"
K. Fujise, T. Saibara, T. Iwanaga, E. Tsurumaki, S. Toyota,
Chem. Lett., 2019, 48, 166-169. Abstract


"Synthesis and Conformational Analysis of 10-Mesitylanthracene-1,8-diyl Oligomers"
S. Toyota, T. Saibara, K. Fujise, T. Oki, T. Iwanaga,
Synlett, 2018, 29, 2137-2140. Abstract


"Iterative Synthesis, Structures, and Properties of Anthracene‐Diacetylene Cyclic Oligomers with 10‐Mesitylanthracene‐1,8‐diyl Units"
S. Toyota, M. Yoshikawa, T. Saibara, Y. Yokoyama, T. Komori, T. Iwanaga,
ChemPlusChem, 2019, 84, 643-654. Abstract

This article was selected as "Very Important Paper".


"Inclusion of chlorinated hydrocarbon guests by 9,9′-bianthracene host and its selectivity"
S. Toyota, A. Yokoyama, K. Tanaka, Y. Akaki, T. Iwanaga,
J. Inclusion Phenom. Macrocyclic Chem., 2018, 92(1-2), 129-136. Abstract


"Nano‐Saturn: Experimental Evidence of Complex Formation of an Anthracene Cyclic Ring with C60"
Y. Yamamoto, E. Tsurumaki, K. Wakamatasu, S. Toyota,
Angew. Chem. Int. Ed., 2018, 57(27), 8199-8202. Abstract
Selected as Hot Paper.


"Synthesis and Electronic Properties of Length-Defined 9,10-Anthrylene-Butadiynylene Oligomers"
M. Nagaoka, E. Tsurumaki, M. Nishiuchi, T. Iwanaga, S. Toyota
J. Org. Chem. , 2018, 83(10), 5784-5790. Abstract