Welcome to the Toyota laboratory!

 "Physical Organic Chemistry" is chemical research area in which we study structure, properties, and reactivity of organic compounds precisely in order to disclose new principles and theories for the relationships between molecular structures and their properties. Based on the idea, we design and synthesize novel organic compounds with unique structure, and we investigate their structure and chemical properties by spectroscopic measurements and theoretical approach.
 Recently, we focus on development of novel "simple yet elegant" π electronic units and we apply them to construct functional 2D or 3D organic architectures. Our research policy is "Design new molecule outside the box, Make the molecule, and Study to find charmy aspects of the molecule".

 We are now recruiting undergraduates, graduated students, and post-Docs. Feel free to contact us if you intend to take a look into our laboratory. Link to address page

Information

 We organize 29th Symposium on Physical Organic Chemistry that will be held on Sep. 6th-8th at Tokyo Institute of Technology.
 See more information, click here.

News

2018.7.19 New paper has been published in Synlett.
2018.5.30 New paper has been published in Journal of Inclusion Phenomena and Macrocyclic Chemistry.
2018.5.30 New paper has been published in Angwandte Chemie International Edition.
2018.5.30 New paper has been published in Chemistry A European Journal.
2018.4.18 New paper has been published in Journal of Organic Chemistry.
2018.4.3 Six new Members joined our laboratory.
2018.3.20 We attended 98th CSJ Annual meeting and gave poster/oral presentations
2018.3.17 New paper has been published in Tetrahedron.
2017.10.23 New paper has been published in Chemistry Letters.
2017.9.25 New paper has been published in Synthesis.
2017.9.7-9 We attended 28th Symposium on Physical Organic Chemistry and gave oral/poster presentations.
2017.8.28 New paper has been published in European Journal of Organic Chemistry.

Recent Papers


"Synthesis and Conformational Analysis of 10-Mesitylanthracene-1,8-diyl Oligomers"
S. Toyota, T. Saibara, K. Fujise, T. Oki, T. Iwanaga,
Synlett, 2018, eFirst. Abstract


"Inclusion of chlorinated hydrocarbon guests by 9,9′-bianthracene host and its selectivity"
S. Toyota, A. Yokoyama, K. Tanaka, Y. Akaki, T. Iwanaga,
J. Inclusion Phenom. Macrocyclic Chem., 2018, Online First. Abstract


"Nano‐Saturn: Experimental Evidence of Complex Formation of an Anthracene Cyclic Ring with C60"
Y. Yamamoto, E. Tsurumaki, K. Wakamatasu, S. Toyota,
Angew. Chem. Int. Ed., 2018, 57(27), 8199-8202. Abstract
Selected as Hot Paper.


"Synthesis and Electronic Properties of Length-Defined 9,10-Anthrylene-Butadiynylene Oligomers"
M. Nagaoka, E. Tsurumaki, M. Nishiuchi, T. Iwanaga, S. Toyota
J. Org. Chem. , 2018, 83(10), 5784-5790. Abstract


"Structures and Photophysical Properties of a 1,8-Anthrylene-Ethenylene Cyclic Tetramer"
M. Inoue, T. Komori, T. Iwanaga, S. Toyota
Chem. Lett., 2017, Advance Publication. Abstract


"Facile Synthesis of Rubicenes by Scholl Reaction"
M. Kawamura, E. Tsurumaki, S. Toyota
Synthesis, 2017, eFirst. Abstract


"Triple and Quadruple Triptycene Gears in Rigid Macrocyclic Frameworks"
S. Toyota, K. Kawahata, K. Sugahara, K. Wakamatsu, T. Iwanaga
Eur. J. Org. Chem., 2017, (37), 5696-5707. Abstract


"Planar Anthracene-Acetylene Frameworks as Stereogenic Motifs"
S. Toyota, H. Ikeda, T. Iwanaga
ChemPlusChem, 2017, 82(7), 957-966. Abstract


"Synthesis of 1,8-Anthracene-Ethenylene Cyclic Dimers and Related Compounds and Effects of Linkers on their Structures, Electronic Properties, and Dynamic Behavior"
M. Inoue, T. Iwanaga, S. Toyota
Asian J. Org. Chem., 2017, 82(7), 566-574. Abstract


"Synthesis, structures, and properties of 2,5-dianthrylthiophene derivatives"
S. Toyota, M. Nishiuchi, T. Iwata, T. Yamauchi, T. Iwanaga, M. Hasegawa
Can. J. Chem., 2017, 95(3), 286-291. Abstract


"Intramolecular Charge-Transfer Interaction of Donor-Acceptor-Donor Arrays Based on Anthracene Bisimide"
T. Iwanaga, M. Ogawa, T. Yamauchi, S. Toyota
J. Org. Chem., 2016, 81(10), 4076-4080. Abstract


'Macrocyclic 2,7-Anthrylene Oligomers'
Y. Yamamoto, K. Wakamatsu, T. Iwanaga, H. Sato, S. Toyota
Chem. Asian J., 2016, 11(9), 1370-1375. Link



'An Enantiopure 5,5′-Bitetracene'
S. Toyota, R. Miyaji, Y. Yamamoto, M. Inoue, K. Wakamatsu, T. Iwanaga,
Eur. J. Org. Chem., 2015, 2015(35), 7648-7651. Link



'Efficient Synthesis and Electronic Spectra of Unsymmetrical 5,12-Diethynyltetracene Derivatives'
T. Iwanaga, Y. Yamamoto, K. Nishioka, S. Toyota
Synthesis, 2015, 47(24), 3997-4007. Link



'Structures, Dynamic Behavior, and Spectroscopic Properties of 1,8-Anthrylene−Ethenylene Cyclic Dimers and Their Substituent Effects'
M. Inoue, T. Iwanaga, S. Toyota
Bull. Chem. Soc. J., 2015, 88(11), 1591-1602. Link



'Cramping an alkyl group by rigid macrocyclic framework'
S. Toyota, T. Oki, M. Inoue, K. Wakamatsu, T. Iwanaga,
Chem. Lett., 2015, 44(7), 978-980. Link



'Chemistry of Anthracene-Acetylene Oligomers XXV: On-Surface Chirality of a Self-Assembled Molecular Network of a Fan-Blade-Shaped Anthracene-Acetylene Macrocycle with a Long Alkyl Chain'
T. Tsuya, K. Iritani, K. Tahara, Y. Tobe, T. Iwanaga, S. Toyota,
Chem. Eur. J., 2015, 21(14), 5520-5527. Link