連絡先

〒152-8550
東京都目黒区大岡山 2-12-1
EEI棟(環境エネルギーイノベーション棟)7F
701(教授室),
702(准教授室),
703号室(助教・学生居室)
(地図)

TEL: (03)-5734-
2240 (701号室)
2239 (702号室)
2759 (703室)
e-mail: ishitani@chem.
(アドレスにはtitech.ac.jpを付けて下さい)

サイトマップ

MATHEW Siby

役職 Specially Appointed Assistant Professor
住所 〒152-8550 東京都目黒区大岡山2-12-1-NE-2 
EEI棟(環境エネルギーイノベーション棟) 703号室
TEL 03-5734-2759
FAX 03-5734-2759
E-mail mathew.s.aa(+@m.titech.ac.jp)

学歴

2015年 Ph.D graduation: Applied Chemistry (Water splitting, Artificial Photosynthesis) Tokyo Metropolitan University, Tokyo, Japan
Advisor: Prof. Haruo Inoue
Thesis: Thesis Study on Reaction Mechanism of Photooxygenation by Metalloporphyrins
2010年 M.Sc. graduation: Organic Chemistry Mahatma Gandhi University, Kerala, India
Advisor: Prof. Kana M. Sureshan
Thesis: An Attempt Towards the Total Synthesis of Streptopyrrolidine
2008年 B.Sc. graduation: Chemistry Mahatma Gandhi University, Kerala, India

職歴・研究歴

2023年- Specially Appointed Assistant Professor
Tokyo Institute of Technology, Japan
• Electrocatalytic reduction of low concentration carbon dioxide
2021-2023年 Postdoctoral Fellow
National Institute of Advanced Industrial Science and Technology-AIST, Japan
• Development of Inorganic-Organic hybrid perovskite solar cells
2019-2021年 Postdoctoral Fellow
National Institute of Advanced Industrial Science and Technology-AIST, Japan
• Synthesis of functional polymers containing phosphorus in the polymer backbone for high temperature applications
2018年 Research Associate Professor
Tokyo Metropolitan University, Tokyo, Japan
• Artificial photosynthesis
2015-2018年 Postdoctoral Research Associat
Tokyo Metropolitan University, Tokyo, Japan
• Artificial photosynthesis
• Laser flash photolysis study of reaction intermediates and kinetics of water oxidation
2011-2012年 Research Assistant
National Institute of Interdisciplinary Science and Technology (NIIST-CSIR), India
• Multi-step organic synthesis and characterization of synthetic analogous of variants of Glycolipids
• Modification of iminosugar derivatives and etherification with lipids

Publication

22. “Molecular Characteristics of Water-Insoluble Tin-Porphyrins for Designing the One-Photon-Induced Two-Electron Oxidation of Water in Artificial Photosynthesis”
A. Thomas, Y. Ohsaki, R. Nakazato, F. Kuttassery, S. Mathew, S. N. Remello, H. Tachibana, H. Inoue,
Molecules, 28.4 (2023): 1882.
21. “Depolymerization of robust polyetheretherketone to regenerate monomer units using sulfur reagents”
Y. Minami, N. Matsuyama, Y. Takeichi, R. Watanabe, S. Mathew, Y. Nakajima,
Communications Chemistry, 6.1 (2023): 14.
20. “One‐Pot Synthesis of Polymers Containing P-C Bonds in the Main Chain”
S. Mathew, Y. Naganawa, F. Jiang, R. Wischert, S. Streiff, P. Metivier, Y. Nakajima,
Macromolecular Rapid Communications,(2023): 2200921.
19. “Suppressing hydrogen bonds and controlling surface dipole: effective passivation for hydrophobic perovskite photoabsorber layers in solar cells”
N. Nishimura, S. Mathew, T. N. Murakami,
New Journal of Chemistry, 47.9 (2023): 4197-4201.
18. “A supramolecular aluminium-based molecular catalyst for water oxidation into H2O2 in saline water”
Mathew, S., A. Sebastian, F. Kuttassery, Y. Yamauchi, T. Isobe, T. Hatanaka, Y. Funahashi, H. Tachibana, H. Inoue,
Sustainable Energy & Fuels, 6.18 (2022): 4256-4264.
17. “Acid-base equilibria of axial ligand and peripheral pyridyl group with stepwise formation of nine species of aluminum (III) tera (4-pyridyl) porphyrin”
Mathew, S.; Sebastian, A.; Kuttassery, F.; Takagi, S.; Tachibana, H.; Inoue, H.,
Inorganica Chimica Acta, 526 (2021): 120529.
16. “Two-electron oxidation of water to form hydrogen peroxide initiated by one-electron oxidation of Tin (IV)-porphyrins”
Ohsaki, Y.; Thomas, A.; Kuttassery, F.; Mathew, S.; Remello, S. N.; Shimada, T.; Ishida, T.; Takagi, S.; Tachibana, H.; Inoue, H.,
Journal of Photochemistry and Photobiology A: Chemistry, 401 (2020): 112732.
15. “Protolytic behavior of water-soluble zinc (II) porphyrin and the electrocatalytic two-electron water oxidation to form hydrogen peroxide”
Sebastian, A.; Remello, S. N.; Kuttassery, F.; Mathew, S.; Ohsaki, Y.; Tachibana, H.; Inoue, H.,
Journal of Photochemistry and Photobiology A: Chemistry, 400 (2020): 112619.
14. “How one-photon can induce water splitting into hydrogen peroxide and hydrogen by aluminum porphyrins. Rationale of the thermodynamics”
Kuttassery, F.; Mathew, S.; Tachibana, H.; Inoue, H.,
Sustainable Energy & Fuels , 4.4 (2020): 1945-1953.
13. “Water splitting on aluminum porphyrins to form hydrogen and hydrogen peroxide by one photon of visible light”
Kuttassery, F.; Sagawa, S.; Mathew, S.; Nabetani, Y.; Iwase, A.; Kudo, A.; Tachibana, H.; Inoue, H.,
ACS Applied Energy Materials, 2.11 (2019): 8045-8051.
12. “Promotive Effect of Bicarbonate Ion on Two‐Electron Water Oxidation to Form H2O2 Catalyzed by Aluminum Porphyrins”
Kuttassery, F.; Sebastian, A.; Mathew, S.; Tachibana, H.; Inoue, H.,
ChemSusChem, 12.9 (2019): 1939-1948.
11. “Alternative route to bypass the bottle-neck of water oxidation: Two-electron oxidation of water catalyzed by earth-abundant metalloporphyrins”
Kuttassery, F.; Mathew, S.; Remello, S. N.; Thomas, A.; Sano, K.; Ohsaki, Y.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
Coordination Chemistry Reviews, 377 (2018): 64-72.
10. “How does the tin (IV)-insertion to porphyrins proceed in water at ambient temperature?: Re-investigation by time dependent 1H NMR and detection of intermediates”
Ohsaki, Y.; Thomas, A.; Kuttassery, F.; Mathew, S.; Remello, S. N.; Nabetani, Y.; Shimada, T.; Takagi, S.; Tachibana, H.; Inoue, H.,
Inorganica Chimica Acta, 482 (2018): 914-924.
9. “Protolytic behavior of axially coordinated hydroxy groups of Tin (IV) porphyrins as promising molecular catalysts for water oxidation”
Thomas, A.; Kuttassery, F.; Mathew, S.; Remello, S. N.; Ohsaki, Y.; Yamamoto, D.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
Journal of Photochemistry and Photobiology A: Chemistry , 358 (2018): 402-410.
8. “Photochemical hydrogen evolution on metal ion surface-grafted TiO2-particles prepared by sol/gel method without calcination”
Kuttassery, F.; Yamamoto, D.; Mathew, S.; Remello, S. N.; Thomas, A.; Nabetani, Y.; Iwase, A.; Kudo, A.; Tachibana, H.; Inoue, H.,
358 (2018): 386-394.
7. “Two‐electron oxidation of water through one‐photon excitation of aluminium porphyrins: molecular mechanism and detection of key intermediates”
Mathew, S.; Kuttassery, F.; Remello, S. N.; Thomas, A.; Yamamoto, D.; Onuki, S.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
ChemPhotoChem, 2.3 (2018): 240-248.
6. “Two-electron oxidation of water to form hydrogen peroxide catalysed by silicon-porphyrins”
Remello, S. N.; Kuttassery, F.; Mathew, S.; Thomas, A.; Yamamoto, D.; Nabetani, Y.; Sano, K.; Tachibana, H.; Inoue, H.,
Sustainable Energy & Fuels , 2.9 (2018): 1966-1973.
5. “One Electron‐Initiated Two‐Electron Oxidation of Water by Aluminum Porphyrins with Earth's Most Abundant Metal”
Kuttassery, F.; Mathew, S.; Sagawa, S.; Remello, S. N.; Thomas, A.; Yamamoto, D.; Onuki, S.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
ChemSusChem, 10.9 (2017): 1909-1915.
4. “Facile synthesis of water-soluble cationic tin (IV) porphyrins and water-insoluble tin (IV) porphyrins in water at ambient temperature”
Thomas, A.; Kuttassery, F.; Remello, S. N.; Mathew, S.; Yamamoto, D.; Onuki, S.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
Bulletin of the Chemical Society of Japan, 89.8 (2016): 902-904.
3. “One-Pot Facile Synthesis of Water-Soluble Cationic Aluminum (III) Porphyrins in a Unique Heterogeneous System at Ambient Temperature”
Mathew, S.; Kuttassery, F.; Yamamoto, D.; Onuki, S.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
Bulletin of the Chemical Society of Japan, 89.3 (2016): 334-336.
2. “Photochemical oxygenation of cyclohexene with water sensitized by aluminium (III) porphyrins with visible light”
Mathew, S.; Kuttassery, F.; Gomi, Y.; Yamamoto, D.; Kiyooka, R.; Onuki, S.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
Journal of Photochemistry and Photobiology A: Chemistry, 313 (2015): 137-142.
1. “Artificial Photosynthesis Sensitized by Metal Complexes: Utilization of a Ubiquitous Element”
Kuttassery, F.; Mathew, S.; Yamamoto, D.; Onuki, S.; Nabetani, Y.; Tachibana, H.; Inoue, H.,
Electrochemistry, 82.6 (2014): 475-485.

Chapter

受賞歴

2012-2015年 Asian Human Resource Fund (AHRF) Fellowship, Japan (19000$/annum)
2014年 Best poster award in ICARP-2014, Japan
2011年 National Eligibility Test (NET) for lectureship in Chemical Science, India

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